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SYNTHESIS OF SMALL MOLECULE THERAPEUTICS UTILIZING RHODIUM
CARBENOID CHEMISTRY
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Synthesis and Excited State Dynamics of Oligothiophene-Nitronyl
Nitroxides
2 of 50
Development of Transition Metal Catalyzed Metallonitrene and Metallocarbene Group Transfer Reactions
3 of 50
Development of a novel stereo-selective synthetic route towards
Pumiliotoxin C, potent neurotoxin, via asymmetric
Diels-Alder and sequential protonation-nucleophilic addition as key
reaction steps
4 of 50
Synthesis of 3-Methyl-TpMo(CO)2(5-Oxo-Pyranyl)
Organometallic Scaffold and Its Application in Forming Quaternary
Center at a Ring Junction via an Oxidative
Annulation-Demetalation Cascade
5 of 50
Optimization of Dual-tropic CXCR4/CCR5 HIV-1 Entry Inhibitors and a
Market Analysis
6 of 50
Anti-bacterial Potential of the Genus Rubus
7 of 50
Towards the Development of Non-Toxic Therapeutics in the Fight
Against Cancer
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Expanding the scope of donor/acceptor rhodium-carbene chemistry
9 of 50
Synthetic Studies Toward Methanoquinolizidine-Containing
Akuammiline Alkaloids
10 of 50
Exo-mode oxacyclization strategies for synthesis of
trans-fused polycyclic ethers: the ABC ring sector of
brevenal
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Investigations of exo-Mode Oxacyclizations for the Synthesis of
Cyclic Ethers
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Synthetic Studies Toward Cyclobutyl Nucleoside Analogs for the
Treatment of Hepatitis C Virus
13 of 50
Use of Furans as Vehicles for Heterocyclic Synthesis: Anaza-Achmatowicz Approach to Piperidine Alkaloids, a Novel OxidativeRoute to Acyloxypyrrolinones, and IMDAF Studies Toward a Synthesisof Minfiensine and Morphine
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Metallonitrene/Alkyne Cascade Reactions: Development of a
Versatile Process for Organic Synthesis
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I. Organometallic Enantiomeric Scaffolding: Total Synthesis of(-)-Adaline and (-)-Adalinine Using a Key 5-Oxo-PyridinylMolybdenum Scaffold and Featuring a SemipinacolRearrangment/1,5-"Michael-like" Sequence.II. Exchange Reactions of 1-Alkoxy and 1-Sulfonyloxy 3-AllylMolybdenum Complexes
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Incorporating Transition Metal Organometallic Chemistry into the
Introductory Organic Chemistry Course
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Asymmetric Synthesis of 8-oxabicyclo[3.2.1]octane Derivatives
Using a Chiral Dirhodium Catalyst
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Part I: Design, Synthesis and Biological Evaluation of C6-C8 Bridged Epothilone AnalogsPart II: Discovery of Small Molecule CXCR4 Antagonists
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Enantiomeric Scaffolds. Molybdenum Pyranyl π-Complexes for the Asymmetric Construction of Oxa-Heterocycles
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Synthetic Studies Towards the Total Synthesis of Myrtoidine
21 of 50
A menthol derived synthon for preparing homoallylic alcohols
bearing three contiguous elements of stereochemistry and Progress
towards a synthon with two centers of reactivity for the allylation
of two different aldehydes
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Impact of Silyl Ethyl Esters on the Rhodium(II)-Catalyzed
Transformations of Donor/Acceptor Carbenes
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Design, Synthesis and Biological Evaluation of C4-C9 Bridged
Epothilone Analogs
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Navigating the Roads to Drug Discovery: Part 1: Design, Synthesis,
and Biological Evaluation of a Novel Class of Allosteric Modulators
of N-Methyl-D-Aspartate Receptor Function Part 2: Discovery of
Novel Tetrahydroisoquinoline (THIQ)-Based CXCR4 Antagonists and
Conformational Analysis of Structurally Similar CXCR4 Antagonists
25 of 50
Development of a Redox-Active Ligand Framework: A Novel Approach towards Reactivity in C−H Functionalization Reactions
26 of 50
Synthesis and Characterization of Organic and Inorganic
Compounds with Biological Applications
27 of 50
Ring Chain Isomerism: Ligands for Mediating Two-Electron
Reactivity with First-Row Transition Metals
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Deoxy-Amine Nucleoside Polymers (dANPs) to Control Gene Expression
29 of 50
Studies toward the total synthesis of altromycin natural products
30 of 50
CYCLOADDITIONS AND YLIDE CHEMISTRY OF DONOR/ACCEPTOR- SUBSTITUTED
CARBENES FROM THERMAL DECOMPOSITION OF ARYLDIAZOCARBONYL COMPOUNDS
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[5+2] Cycloadditions to Form Oxobicyclo[3.2.1]octanes
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Design and Development of Novel Methods for C-H Functionalization
for Amination and C-C Bond Formation
33 of 50
Development of a Novel Cascade Cyclization Reaction and its
Application Towards the Total Synthesis of Malagashanine: A
Chloroquine Efflux Inhibitor
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Application of IMDAF and Rh(II)-Catalyzed Cascade Reactions forTotal Synthesis of Natural Products
35 of 50
RHODIUM CATALYZED ASYMMETRIC TRANSFORMATIONS OF VINYLCARBENOIDS
36 of 50
Design, Synthesis, and Biological Evaluation of Subunit-Selective
N-Methyl-D-Aspartate Receptor Modulators
37 of 50
Synthesis and Characterization of Unusal Amphiphiles Part I. Nonsteroidal Facial Amphiphiles Part II. Diketopiperazine Derived Surfactants
38 of 50
Chiral dirhodium catalysts design, synthesis and application in
asymmetric carbenoid transformations and silver-catalysis of
vinylogous fluorination
39 of 50
Design, Synthesis, and Biologic Evaluation of
Tetrahydroisoquinoline-Based CXCR4 Modulators
40 of 50
Organometallic Enantiomeric Scaffolds in the Synthesis of
Alkaloids: I. Homo-SN2´-like Reaction/Annulative Demetallation
and the Application in the Synthesis of (+)-Isofebrifugine II.
Uncatalyzed Electrophilic C-C Bond Forming Reactions of Pyranyl and
Pyridinyl Molybdenum Complexes
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ASYMMETRIC REACTIONS OF DONOR/ACCEPTOR RHODIUM CARBENOIDS: FROM
FORMAL CYCLOADDITIONS TO C-H INSERTION
42 of 50
Part 1: Stereoselective Synthesis of Quaternary Center BearingAzetines and β-Amino Acid Derivatives. Part 2: Natural andEnantiomeric Progesterone Analogues for the Treatment of TraumaticBrain Injury
43 of 50
Synthesis of Those Sectors of Saccharomicin A and B ContainingSaccharosamine and the Discovery of a Novel 4-H-1,3-OxazineSynthesis
44 of 50
Computational Studies of Ligand Protein Interactions Part I: TheT-Taxol Conformation Part II: Elucidating Interdependent BindingSites on Tubulin
45 of 50
The Polyoxometalate / NOx / Brx Catalystsfor Aerobic Sulfoxidations
46 of 50
Mild Amide and Peptide Constructions by the Condensation of
O-Silylthionoesters with Amines and Metal Mediated Cross-Coupling
Reactions for Carbon-Carbon Bond Formation
47 of 50
Synthesis and Reactivity of Benzo[1,3,2]dithiazole 1,1-dioxides: Implications in Acylative Redox Dehydration
48 of 50
Progress Toward a Common Intermediate for C1 Modified
Enigmols
49 of 50
Synthesis of Ellagic Acid Glycoside Derivatives found in Rubus
ulmifolius
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