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Synthesis of 3-Methyl-TpMo(CO)2(5-Oxo-Pyranyl)
Organometallic Scaffold and Its Application in Forming Quaternary
Center at a Ring Junction via an Oxidative
Annulation-Demetalation Cascade
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I. Organometallic Enantiomeric Scaffolding: Total Synthesis of(-)-Adaline and (-)-Adalinine Using a Key 5-Oxo-PyridinylMolybdenum Scaffold and Featuring a SemipinacolRearrangment/1,5-"Michael-like" Sequence.II. Exchange Reactions of 1-Alkoxy and 1-Sulfonyloxy 3-AllylMolybdenum Complexes
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Controlling the Synthesis of New Polyoxometalates and RemovingTheir Crystallographic Disorder
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