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SYNTHETIC AND QUANTUM-CHEMICAL EXPLORATION OF THE SELECTIVITY OF
DONOR/ACCEPTOR-SUBSTITUTED METALLOCARBENOIDS
1 of 100
Synthetic Studies for Heterocycle Synthesis Part I:
Intra/intermolecular Olefin Diamination for the Stereoselective
Synthesis of 3-Aminopiperidines Part II: Total Synthesis of
Malagashanine and Synthetic Studies Toward Related Alkaloids
2 of 100
Characterization of Novel HydX Protein and its Involvement in the
Formation of the Active Site in [Fe-Fe] Hydrogenases
3 of 100
Synthesis, characterization, and in vitro biological testing
of gold(III) polypyridyl compounds: Insights into cytotoxicity of
neutral distorted square pyramidal complexes
4 of 100
Synthesis of Novel Anti-Cancer Compounds Based on Sphingolipid
Analogs
5 of 100
Ligand Design Strategies for Regulating Small Molecule Binding and
Reactivity at Transition Metal Centers
6 of 100
Expanding the Scope of Donor/Acceptor Rhodium-Carbene Chemistry
7 of 100
Synthesis and Reactivity of Novel Benzoisothiazolone
Organocatalysts for Redox Condensation Reactions
8 of 100
EXPLORATION OF HIGH SYMMETRY DIRHODIUM CATALYSTS AND THE REACTION
OF DONOR/ACCEPTOR CARBENOIDS WITH ALCOHOLS
9 of 100
TRANSITION METAL CATALYZED STEREOSELECTIVE TRANSFORMATIONS OF
ALKYNES AND DONOR/ACCEPTOR CARBENOIDS
10 of 100
Design, Synthesis, and Utilization of Iridium(III)
Bis(oxazolinyl)phenyl and Iridium(III) Bis(imidazolinyl)phenyl
Complexes for Catalytic Enantioselective Atom Transfer C-H
Functionalization
11 of 100
Investigation and Modeling of Binding Modes of Novel Small-Molecule
Nox2 Inhibitors
12 of 100
I. Self-Assembly of Thioether-Modified Cationic Surfactants
II. Electrostatic Binding among Equilibrating 2-D and 3-D
Self-Assemblies
13 of 100
Chapter 1. Total synthesis of Fumonisin B1 Chapter 2.
Synthesis of Unnatural Sphingolipids: 1-deoxy-5-hydroxysphinganine
and its diastereomers Chapter 3. Development of Methodology:
Synthesis of cis- and trans-homoallylic alcohols
Chapter 4. Human Milk Oligosaccharides: Synthesis of Natural and
Unnatural oligomers
14 of 100
Design, Synthesis, and Biological Evaluation of Subunit
Selective N-Methyl-D-Aspartate Receptor Modulators
15 of 100
Directed Evolution and Computational Design of Nucleoside Analog
Kinases
16 of 100
I. A New Approach to the Synthesis of a Key 5-Oxo-Pyridinyl
Molybdenum Scaffold. II. Oxidative Demetalation of
η3-Allylmolybdenum Complexes with an Oxygen
Nucleophile; Application to the Synthesis of (+)-Isofebrifugine
Analogs
17 of 100
Synthesis, characterization, and biological stabilities of
gold(III) di-2-pyridyl and sec-butyl-phenanthroline
complexes
18 of 100
I. Development of a passive sampler and static sampling chamber
to measure personal exposure to gaseous PAHs. II. Method
development for determination of current-use and persistent
pesticides in cow milk, human breast milk, baby formulas, and human
serum using gas chromatography tandem mass spectrometry.
19 of 100
Orientation and Vibrational Dynamics of Rhenium Bipyridyl
CO2-Reduction Catalysts on Model Electrode
Surfaces
20 of 100
Efficient implementations of quantum chemistry methods for strongly
correlated electrons
21 of 100
Synthesis of protein-based polymers with the potential to form
physically and covalently cross-linked networks
22 of 100
Simulations of Lipid Sorting Effects near Transmembrane
Peptide
23 of 100
Amyloid Conformational Diversity Accessed By Truncations of a
Native Protein Fold
24 of 100
Degradation of pesticides in food and beverages: Implications for
risk assessment
25 of 100
Coordination Mode Versatility and Intramolecular Bond Activation
in Metal Complexes Supported by a Family of Tris(amidato)amine
Ligands
26 of 100
Synthesis, Characterization, and Biological Data for Potential
Anticancer Gold(III) Complexes.
27 of 100
Identification of Small Molecule Inhibitors of I-κB
Kinase
28 of 100
Synthesis and Characterization of
N-alkyl-3-(2,4-dichlorophenyl)-N-fluoroalkyl-2,5-
dimethylpyrazolo[1,5-a]pyrimidin-7-amines as Potential CRF1
Receptor PET Radiotracers
29 of 100
Senior Honors Recital
30 of 100
Expanding the Scope of Donor/Acceptor Carbenes and the Synthesis of
Novel Therapeutic Agents for Cocaine Abuse
31 of 100
Creation of Tubular α− Helical Assemblies Through
Seven-Helix Coiled Coils
32 of 100
Part I: Synthesis of Cyclobutyl
Nucleoside Analogs That Mimic AZT for Inhibition of the K65R HIV-1
Reverse Transcriptase Mutant
Part II: Synthesis and Evaluation of
Truncated Triptolide Analogs to Suppress Chronic Inflammation
33 of 100
Incorporating the Scientific Contributions of Research Faculty into
the Chemical Education of Undergraduate Students at Emory
University
34 of 100
Quantum Confined Semiconductor Nanocrystals for Efficient Charge
Separation and Solar-to-fuel Conversion
35 of 100
Modular Synthesis of Polyketide Natural Products: Synthesis of
the C9-C27 Degradation Product of Aflastatin A and Total Synthesis
of Fostriecin
36 of 100
Development of a Copper Catalyzed Aminoacetoxylation Reaction of
Olefins, Development of an Intermolecular and Diastereoselective
Iminium Cascade Reaction and Studies Towards the Synthesis of a
Malagasy Alkaloid
37 of 100
Ability of a Connexin Chaperone to Rescue Oculodentodigital
Dysplasia Mutant Connexin 43
38 of 100
TARGETING MIXED LINEAGE LEUKEMIA AS ANTICANCER THERAPY FOR
INFANTILE ACUTE LYMPHOBLASTIC LEUKEMIA THROUGH THE SYNTHESIS OF
NOVEL COMPOUNDS
39 of 100
Recombinant Site Specific Labeling of Proteins with IR Probes
40 of 100
Stereocontrolled Synthesis of Ketones bearing Stereogenic Centers
by Desulfitative Cross-Coupling of Thiol Esters and Organostannanes
41 of 100
Chiral Materials and Water Oxidation Catalysts from
Transition-Metal-Substituted Polyoxometalates
42 of 100
Dynamics Calculations of Several Atmospheric Reactions on Global
Potential Energy Surfaces
43 of 100
Chapter 1: The development of a model system for the B-ring of
brevenal and methods for the formation of seven-membered rings.
Chapter 2: Iterative alkyne-epoxide cross-couplings toward the
total synthesis of PM toxin A. Chapter 3: The development of
synthons for 1,3-dimethylallylation of aldehydes.
44 of 100
Enzyme Engineering
45 of 100
Synthesis of 2'-Fluoro-2',3'-Dideoxynucleosides as Inhibitors of
Hepatitis C Virus RNA-Dependent RNA Polymerase; Synthesis of
Cyclobutyl Phosphonate and Phosphoramidate Prodrugs for Inhibition
of HIV Reverse Transcriptase
46 of 100
Nanoscale Tools to Expand the Biophysical Understanding of
Epidermal Growth Factor Receptor Function
47 of 100
Programmed Self-assembly of Coiled-coil Peptides
48 of 100
Synthesis and Reactivity of Transition Metal Complexes Supported by
a Neutral Tetraamine Ligand Containing N,N'-dimethylaniline
Units
49 of 100
Gold(III) Complexes as Potential Anticancer Metallotherapeutics
50 of 100
In Situ Kinetic Studies of Reactions Involving Dirhodium(II)
Donor/Acceptor Carbenes
51 of 100
Globin Coupled Sensor Signaling in P. carotovorum: A Model of
Biofilm Regulation through Oligomerization of Diguanylate Cyclases
52 of 100
Investigation of C-H Bond Oxidation Reactions: I. Asymmetric
Amination of C-H Bonds Using Ruthenium(II) Catalysts II.
Investigation of Structural Determinants of Monoamine Oxidase B
53 of 100
Use of Receptor-Based Drug Design and Applications in the Study
of finding antagonists for MD-2/TLR4, GLP and CXCR4
54 of 100
Explorations of Metallocarbene and Metallonitrene Reactive
Intermediate Chemistry for the Development of Synthetically Useful
New Reactions
55 of 100
Widening the Active Site of Bacillus circulans Xylanase
by Amino Acid Insertion
56 of 100
Progress Toward the Total Synthesis of PM-toxin A And Future
Development of Mild Lewis Acid Activated Alkynylation of Epoxides
57 of 100
A Thorough Investigation of the Characteristic Phosphorus Couplings
and 31P NMR Analysis in Attempts to Synthesize an Ifosfamide Analog
58 of 100
Interfacial Electron Transfer Dynamics between Organic Molecular
Adsorbates and Semiconductor Nanoparticles
59 of 100
From Aptamer to Riboswitch: High-throughput Screens and Selections
for the Identification and Creation of Synthetic Riboswitches
60 of 100
Biomaterial Design: Human Tropoelastin
61 of 100
Rhodium(II)-Catalyzed Asymmetric Transformations and Their
Applications in The Development of Novel CNS Drug Candidates
62 of 100
Photoreleasable dynamic interfaces to control hybrid
cell-supported lipid membrane junctions
63 of 100
Synthesis and Characterization of Organic and Inorganic
Compounds with Biological and Material Applications
64 of 100
Theoretical Studies of Unusual Molecular Vibrational
Dynamics
65 of 100
Development of Monocarbonyl Curcumin Analogues Towards Treating
Tuberculosis and Cancer
66 of 100
Synthesis of Highly Functionalized Pyrroles Using a Dirhodium
Catalyst
67 of 100
SYNTHESIS OF CYCLOPROPANES AND DIHYDROFURANS BY METAL CARBENOID
REACTIONS
68 of 100
Immobilization of Polyoxometalates for Electrochemical Water
Oxidation
69 of 100
Part I: Design, Synthesis, and Biological Activity of NMDA
Receptor Antagonists
Part II: Design and Synthesis of Measles Virus Inhibitors
70 of 100
Conformational evolution in amyloid self-assembly
71 of 100
Validation of Receptor-Based Drug Design and Applications in the
Study of IKKs, Truncated Taxane and LRH-1
72 of 100
Rhodium Alkenylcarbenes: Novel Reactivity and Precursors
73 of 100
Charge Separation Dynamics between Semiconductor Nanoparticles and
Molecular Adsorbates
74 of 100
Exploring Catalytic Properties of Polyoxometalates in Aerobic
Decontamination and Water Oxidation
75 of 100
Investigations Into the Design of Electronically Responsive Ligands
76 of 100
Synthesis of Ellagic Acid Glycoside Derivatives found in Rubus
ulmifolius
77 of 100
Gated Proton Transfer Reactions at Low Temperatures in
D2O

78 of 100
CO2 Reduction Catalyzed by Mercaptopteridine
79 of 100
Innocent and Non-innocent Countercation Interactions in Transition
Metal Oxidation Catalysts
80 of 100
Progress Toward a Common Intermediate for C1 Modified
Enigmols
81 of 100
Mild Amide and Peptide Constructions by the Condensation of
O-Silylthionoesters with Amines and Metal Mediated Cross-Coupling
Reactions for Carbon-Carbon Bond Formation
82 of 100
Design, Synthesis, and Biological Evaluation of Subunit-Selective
N-Methyl-D-Aspartate Receptor Antagonists
83 of 100
Spectroscopic studies of molecules that challenge computational
chemistry
84 of 100
Tumor Necrosis Factor-alpha mediated transactivation of the
Epidermal Growth Factor Receptor and Keratinocytes
85 of 100
Development of High Throughput Screening Methods to Identify
Potential Therapeutic Oxygen Carriers
86 of 100
Polyoxometalates as Water Oxidation Catalysts and Their Use in
Light-Driven Water Splitting
87 of 100
Electron Transfer Kinetics in a Triad Photo-anode for Light-driven
Water-splitting
88 of 100
ASYMMETRIC REACTIONS OF DONOR/ACCEPTOR RHODIUM CARBENOIDS: FROM
FORMAL CYCLOADDITIONS TO C-H INSERTION
89 of 100
Organometallic Enantiomeric Scaffolds in the Synthesis of
Alkaloids: I. Homo-SN2´-like Reaction/Annulative Demetallation
and the Application in the Synthesis of (+)-Isofebrifugine II.
Uncatalyzed Electrophilic C-C Bond Forming Reactions of Pyranyl and
Pyridinyl Molybdenum Complexes
90 of 100
Design, Synthesis, and Biologic Evaluation of
Tetrahydroisoquinoline-Based CXCR4 Modulators
91 of 100
Gas Phase Molecular Spectroscopy: Electronic Spectroscopy of
Combustion Intermediates, Chlorine Azide Kinetics, and
Rovibrational Energy Transfer in Acetylene
92 of 100
Chiral dirhodium catalysts design, synthesis and application in
asymmetric carbenoid transformations and silver-catalysis of
vinylogous fluorination
93 of 100
The Effect of Methylene Spacers on the Spectral, Electrochemical,
Structural, and Photophysical Properties and Electron Injection
Dynamics of Bis(4,4'-disubstituted-2,2'- bipyridyl) Ruthenium(II)
Dye Analogues and The Effect of Alkali Metal Ions on the Structure
and Spectroscopy of a Tripodal Co(II) Complex
94 of 100
Design, Synthesis, and Biological Evaluation of Subunit-Selective
N-Methyl-D-Aspartate Receptor Modulators
95 of 100
Single Quantum Dot Electron Transfer Dynamics
96 of 100
High Resolution THz Spectroscopy of Astrophysically Relevant Ions
97 of 100
Application of fluorescent nucleoside analogs in direct evolution
of Drosophila melanogaster deoxyribonucleoside kinase
98 of 100
Kinetic Effects of Circular Permutation and Lid Swapping
Techniques on Candida antarctica Lipase B
99 of 100
Single- and Double-Component Atomistic Models of
Phosphatidylcholine Lipid Bilayers in the Gel and Liquid
Crystalline Phases
100 of 100