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Synthetic Studies for Heterocycle Synthesis Part I:
Intra/intermolecular Olefin Diamination for the Stereoselective
Synthesis of 3-Aminopiperidines Part II: Total Synthesis of
Malagashanine and Synthetic Studies Toward Related Alkaloids
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Design, Synthesis, and Utilization of Iridium(III)
Bis(oxazolinyl)phenyl and Iridium(III) Bis(imidazolinyl)phenyl
Complexes for Catalytic Enantioselective Atom Transfer C-H
Functionalization
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Chapter 1. Total synthesis of Fumonisin B1 Chapter 2.
Synthesis of Unnatural Sphingolipids: 1-deoxy-5-hydroxysphinganine
and its diastereomers Chapter 3. Development of Methodology:
Synthesis of cis- and trans-homoallylic alcohols
Chapter 4. Human Milk Oligosaccharides: Synthesis of Natural and
Unnatural oligomers
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Design, Synthesis, and Biological Evaluation of Subunit
Selective N-Methyl-D-Aspartate Receptor Modulators
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Development of a Copper Catalyzed Aminoacetoxylation Reaction of
Olefins, Development of an Intermolecular and Diastereoselective
Iminium Cascade Reaction and Studies Towards the Synthesis of a
Malagasy Alkaloid
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Synthesis of 2'-Fluoro-2',3'-Dideoxynucleosides as Inhibitors of
Hepatitis C Virus RNA-Dependent RNA Polymerase; Synthesis of
Cyclobutyl Phosphonate and Phosphoramidate Prodrugs for Inhibition
of HIV Reverse Transcriptase
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Synthesis and Reactivity of Transition Metal Complexes Supported by
a Neutral Tetraamine Ligand Containing N,N'-dimethylaniline
Units
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In Situ Kinetic Studies of Reactions Involving Dirhodium(II)
Donor/Acceptor Carbenes
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Investigation of C-H Bond Oxidation Reactions: I. Asymmetric
Amination of C-H Bonds Using Ruthenium(II) Catalysts II.
Investigation of Structural Determinants of Monoamine Oxidase B
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Explorations of Metallocarbene and Metallonitrene Reactive
Intermediate Chemistry for the Development of Synthetically Useful
New Reactions
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Rhodium Alkenylcarbenes: Novel Reactivity and Precursors
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Mild Amide and Peptide Constructions by the Condensation of
O-Silylthionoesters with Amines and Metal Mediated Cross-Coupling
Reactions for Carbon-Carbon Bond Formation
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Tumor Necrosis Factor-alpha mediated transactivation of the
Epidermal Growth Factor Receptor and Keratinocytes
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ASYMMETRIC REACTIONS OF DONOR/ACCEPTOR RHODIUM CARBENOIDS: FROM
FORMAL CYCLOADDITIONS TO C-H INSERTION
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Organometallic Enantiomeric Scaffolds in the Synthesis of
Alkaloids: I. Homo-SN2´-like Reaction/Annulative Demetallation
and the Application in the Synthesis of (+)-Isofebrifugine II.
Uncatalyzed Electrophilic C-C Bond Forming Reactions of Pyranyl and
Pyridinyl Molybdenum Complexes
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Chiral dirhodium catalysts design, synthesis and application in
asymmetric carbenoid transformations and silver-catalysis of
vinylogous fluorination
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RHODIUM CATALYZED ASYMMETRIC TRANSFORMATIONS OF VINYLCARBENOIDS
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Development of a Novel Cascade Cyclization Reaction and its
Application Towards the Total Synthesis of Malagashanine: A
Chloroquine Efflux Inhibitor
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Design and Development of Novel Methods for C-H Functionalization
for Amination and C-C Bond Formation
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[5+2] Cycloadditions to Form Oxobicyclo[3.2.1]octanes
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CYCLOADDITIONS AND YLIDE CHEMISTRY OF DONOR/ACCEPTOR- SUBSTITUTED
CARBENES FROM THERMAL DECOMPOSITION OF ARYLDIAZOCARBONYL COMPOUNDS
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Ring Chain Isomerism: Ligands for Mediating Two-Electron
Reactivity with First-Row Transition Metals
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Impact of Silyl Ethyl Esters on the Rhodium(II)-Catalyzed
Transformations of Donor/Acceptor Carbenes
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A menthol derived synthon for preparing homoallylic alcohols
bearing three contiguous elements of stereochemistry and Progress
towards a synthon with two centers of reactivity for the allylation
of two different aldehydes
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Metallonitrene/Alkyne Cascade Reactions: Development of a
Versatile Process for Organic Synthesis
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Exo-mode oxacyclization strategies for synthesis of
trans-fused polycyclic ethers: the ABC ring sector of
brevenal
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Synthetic Studies Toward Cyclobutyl Nucleoside Analogs for the
Treatment of Hepatitis C Virus
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Investigations of exo-Mode Oxacyclizations for the Synthesis of
Cyclic Ethers
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Synthetic Studies Toward Methanoquinolizidine-Containing
Akuammiline Alkaloids
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Synthesis of 3-Methyl-TpMo(CO)2(5-Oxo-Pyranyl)
Organometallic Scaffold and Its Application in Forming Quaternary
Center at a Ring Junction via an Oxidative
Annulation-Demetalation Cascade
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The Coordination Chemistry of Hydrogen Peroxide
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Progress toward Lewis acid catalyzed asymmetric transformation
of amino alcohols towards influence on the Blakey group synthesis
of malagashanine
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Use of Furans as Vehicles for Heterocyclic Synthesis: Anaza-Achmatowicz Approach to Piperidine Alkaloids, a Novel OxidativeRoute to Acyloxypyrrolinones, and IMDAF Studies Toward a Synthesisof Minfiensine and Morphine
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Enantiomeric Scaffolds. Molybdenum Pyranyl π-Complexes for the Asymmetric Construction of Oxa-Heterocycles
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Application of IMDAF and Rh(II)-Catalyzed Cascade Reactions forTotal Synthesis of Natural Products
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Aerobic, Medal Mediated Ketone Synthesis from Thiol Esters and Boronic Acids
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Chapter 1. Part 1: Novel Synthesis and Biological Evaluation of1,5-Linked D-Mannoseptanosides. Part 2: Synthesis ofD-Glucoseptanosides Chapter 2. Biomimetic Total Synthesis of theProposed Structure of ent-Muzitone
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I. Addressing the Regioselectivity Problem in Organic Synthesis.II. A-B-A-B-A Block Amphiphiles. Balance between Hydrophilic andHydrophobic Segmentation.
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Metal Mediated Cross-Coupling Reactions for Carbon-Carbon andCarbon-Nitrogen Bonds Formation under Neutral pH Conditions
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Utilization of a Michael Addition-Dipolar Cycloaddition Cascade Involving 2,3- bis(Phenylsulfonyl)butadiene for Alkaloid Synthesis
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Organometallic Scaffolding as a Practical Approach toDiversity-Oriented Synthesis: Stereo- and RegiocontrolledSequential Functionalization of Pyranylalkylidene AllylmolybdenumComplexes
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Part I: Synthesis of Cyclobutyl Nucleoside and NucleotideAnalogues as HIV-1 Reverse Transcriptase InhibitorsPart II: Improvement of Glycosylation Regioselectivity in PurineNucleoside Analogue SynthesisPart III: Enantioselective Synthesis ofβ-D-Dioxolane-T andβ-D-FDOC
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Expanding the Scope of Reactions and Applications of Donor/Acceptor Metallocarbenes
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Development of a Redox-Active Ligand Framework: A Novel Approach towards Reactivity in C−H Functionalization Reactions
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The Stabilization of Reactive Copper Complexes Using 1,4,7-Triazacyclononane Derivatives
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Investigating Sustainable Precious Metal Catalysis: Routine Dirhodium Catalyzed Carbene Reactions with High Yield and Enantioselectivity at Low Loadings
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Synthetic Studies Towards the Total Synthesis of Myrtoidine
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A Methodological Study of Enantioselective Dirhodium(II)-Catalyzed Cyclopropanations at Low Catalyst Loadings
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Senior Honors Euphonium Recital
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Development of Transition Metal Catalyzed Metallonitrene and Metallocarbene Group Transfer Reactions
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Practical Enhancement and Applications of Dirhodium Catalyzed Reactions of Donor/Acceptor Carbenes
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Part 1. Discovery of a Fluorinated Enigmol Analog with Enhanced Pharmacokinetic and Anti-Tumor Properties. Part 2. Preferential Activation of Metabotropic Glutamate Receptor 3 over Metabotropic Glutamate Receptor 2
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Allylic C-H Functionalization of Disubstituted Olefins via Rhodium-π-Allyl Intermediates and Development of a Chiral Cyclopentadienyl Catalyst
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Cobalt Catalyzed Intramolecular Cyclization of Acyclic Alkenols for Polycyclic Ether Synthesis
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Reductive Processes Enabled by Photoredox for the Synthesis and Modification of Pharmaceutically Relevant Molecules
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Arene Dearomatization via Radical Hydrofunctionalization
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Dearomative Photocatalytic Hydroalkylation and Lipophilic Prodrugs
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Kinetic Studies of Rhodium(III)-Catalyzed Allylic C-H Amination of Disubstituted Olefins
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Development of Bis(amidophenyl)amine Redox-active Ligands for Multi-electron Catalysis by Transition Metals
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Site-selective and Stereoselective Functionalization of Non-Activated C–H Bond
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The Development of Complementary Allylic C-H Amination and Amidation Conditions for the Regioselective Functionalization of Group IX MCp*-π-Allyl Intermediates
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Synthesis of septanose glycals and progress towards endo-mode cyclization of polyepoxides
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Modulating the Catalytic Activity of First-Row Transition Metal Complexes Supported by Redox-Active Ligand Scaffolds
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TOTAL SYNTHESIS AND BIOLOGICAL EVALUATION OF NATURAL PRODUCT MIMICS TOWARDS FUNGAL PATHOGENS
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